ダウンロード数: 339
このアイテムのファイル:
| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| j.jorganchem.2009.01.015.pdf | 541.46 kB | Adobe PDF | 見る/開く |
| タイトル: | Synthesis and luminescent properties of pyrenylvinylene-substituted tripylborane |
| 著者: | Nagata, Yuuya Chujo, Yoshiki |
| 著者名の別形: | 中條, 善樹 |
| キーワード: | Tripylborane Luminescent compound DFT calculation Hydroboration reaction |
| 発行日: | 1-May-2009 |
| 出版者: | Elsevier |
| 引用: | Yuuya Nagata and Yoshiki Chujo. Synthesis and luminescent properties of pyrenylvinylene-substituted tripylborane. Journal of Organometallic Chemistry. 2009, 694(11), 1723-1726. |
| 誌名: | Journal of Organometallic Chemistry |
| 巻: | 694 |
| 号: | 11 |
| 開始ページ: | 1723 |
| 終了ページ: | 1726 |
| 抄録: | A novel luminescent compound, bis((E)-2-pyren-1-yl-vinyl)-2, 4, 6-triisopropylphenylborane (3) was synthesized by hydroboration reaction and was fully characterized. The obtained compound was further investigated by single-crystal X-ray diffraction analysis and DFT calculations. The extended structure tells us their herringbone structures with closely faced pairs of the molecules. Comparing the photoluminescent spectra between solution-state and solid state, the spectrum of the solid state of the compound 3 exhibited dramatically red-shifted fluorescent emission. This change also supports the efficient π-stacking behavior of the compound 3. |
| 著作権等: | Copyright © 2009 Elsevier B.V. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
| URI: | http://hdl.handle.net/2433/123389 |
| DOI(出版社版): | 10.1016/j.jorganchem.2009.01.015 |
| 出現コレクション: | 学術雑誌掲載論文等 |
このリポジトリに保管されているアイテムはすべて著作権により保護されています。