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|Title:||Synthesis and luminescent properties of pyrenylvinylene-substituted tripylborane|
|Author's alias:||中條, 善樹|
|Citation:||Yuuya Nagata and Yoshiki Chujo. Synthesis and luminescent properties of pyrenylvinylene-substituted tripylborane. Journal of Organometallic Chemistry. 2009, 694(11), 1723-1726.|
|Journal title:||Journal of Organometallic Chemistry|
|Abstract:||A novel luminescent compound, bis((E)-2-pyren-1-yl-vinyl)-2, 4, 6-triisopropylphenylborane (3) was synthesized by hydroboration reaction and was fully characterized. The obtained compound was further investigated by single-crystal X-ray diffraction analysis and DFT calculations. The extended structure tells us their herringbone structures with closely faced pairs of the molecules. Comparing the photoluminescent spectra between solution-state and solid state, the spectrum of the solid state of the compound 3 exhibited dramatically red-shifted fluorescent emission. This change also supports the efficient π-stacking behavior of the compound 3.|
|Rights:||Copyright © 2009 Elsevier B.V.|
この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。This is not the published version. Please cite only the published version.
|Appears in Collections:||Journal Articles|
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