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128_2009_6.pdf | 934.25 kB | Adobe PDF | 見る/開く |
タイトル: | Controlled Polymerization by Incarceration of Monomers in Nanochannels |
著者: | Uemura, Takashi Kitagawa, Susumu https://orcid.org/0000-0001-6956-9543 (unconfirmed) |
著者名の別形: | 植村, 卓史 北川, 進 |
キーワード: | Nanochannel PCP Polymer structure Polymerization |
発行日: | 2010 |
出版者: | Springer-Verlag Berlin Heidelberg |
誌名: | Topics in Current Chemistry |
巻: | 293 |
開始ページ: | 155 |
終了ページ: | 173 |
抄録: | Porous Coordination Polymers (PCPs) composed of transition metal ions and bridging organic ligands have been extensively studied. The characteristic features of PCPs are highly regular channel structures, controllable channel sizes approximating molecular dimensions, designable surface potentials and functionality, and flexible frameworks responsive to guest molecules. Owing to these advantages, successful applications of PCPs range from molecular storage and separation to heterogeneous catalysts. In particular, use of their regulated and tunable nanochannels in the field of polymerization has allowed multi-level control of polymerization via control of stereoregularlity, molecular weight, etc. In this chapter, we focus on recent progress in polymerization utilizing the nanochannels of PCPs, and demonstrate why this polymerization system is attractive and promising from the viewpoint of precision control of polymeric structures. |
著作権等: | The original publication is available at www.springerlink.com This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
URI: | http://hdl.handle.net/2433/130697 |
DOI(出版社版): | 10.1007/128_2009_6 |
出現コレクション: | 学術雑誌掲載論文等 |
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