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Title: Synthetic studies of salinosporamide A through the intramolecular hydroamidation of alkynes
Authors: Kamisaki, Haruhi
Kobayashi, Yusuke  kyouindb  KAKEN_id
Kimachi, Tetsutaro
Yasui, Yoshizumi
Takemoto, Yoshiji  kyouindb  KAKEN_id
Author's alias: 竹本, 佳司
Keywords: Rhodium carbonyl complexes
C–H activation
Alkynes
Hydroamidation
γ-Lactams
Issue Date: Jan-2011
Publisher: Elsevier B.V.
Journal title: Journal of Organometallic Chemistry
Volume: 696
Issue: 1
Start page: 42
End page: 45
Abstract: Rhodium-catalyzed intramolecular hydroamidation of alkynes was carried out to construct the synthetic intermediates of a proteasome inhibitor, salinosporamide A. Several alkynyl formamides were synthesized and subjected to the hydroamidation reaction. Some derivatives with a methoxymethyl (MOM) or 2-methoxy-2-propyl (MOP) group near the reaction site were converted to the corresponding lactams in excellent yields.
Rights: © 2010 Elsevier B.V.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
URI: http://hdl.handle.net/2433/134562
DOI(Published Version): 10.1016/j.jorganchem.2010.06.021
Appears in Collections:Journal Articles

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