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Title: Direct synthesis of highly fused perimidines by copper(I)-catalyzed hydroamination of 2-ethynylbenzaldehydes
Authors: Tokimizu, Yusuke
Ohta, Yusuke
Chiba, Hiroaki
Oishi, Shinya  kyouindb  KAKEN_id
Fujii, Nobutaka  KAKEN_id
Ohno, Hiroaki  kyouindb  KAKEN_id
Author's alias: 藤井, 信孝
大野, 浩章
Keywords: C–H arylation
Polyarene
Isoquinoline
Perimidine
Multi-component reaction
Issue Date: Jul-2011
Publisher: Elsevier Ltd.
Journal title: Tetrahedron
Volume: 67
Issue: 29
Start page: 5168
End page: 5175
Abstract: A novel synthesis of highly fused perimidine derivatives was achieved in two steps from 2-alkynylbenzaldehydes. Copper-catalyzed annulation of 2-[(2-bromophenyl)ethynyl]benzaldehydes with 1, 8-diaminonaphthalene produced dihydroisoquinolino[2, 1-a]perimidines bearing a 2-bromophenyl group. Subsequent palladium-catalyzed C–H arylation provided dibenzo[1, 2:7, 8]quinolizino[3, 4, 5, 6-kla]perimidine derivatives in moderate to good yields.
Rights: © 2011 Elsevier Ltd.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
URI: http://hdl.handle.net/2433/143596
DOI(Published Version): 10.1016/j.tet.2011.05.051
Appears in Collections:Journal Articles

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