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ファイル | 記述 | サイズ | フォーマット | |
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j.jmr.2011.09.013.pdf | 2.19 MB | Adobe PDF | 見る/開く |
タイトル: | Nondestructive high-resolution solid-state NMR of rotating thin films at the magic-angle. |
著者: | Inukai, Munehiro Noda, Yasuto https://orcid.org/0000-0003-4971-4023 (unconfirmed) Takeda, Kazuyuki https://orcid.org/0000-0002-6743-0932 (unconfirmed) |
著者名の別形: | 犬飼, 宗弘 |
キーワード: | Solid state NMR Magic angle spinning Thin film |
発行日: | Dec-2011 |
出版者: | Elsevier Inc. |
誌名: | Journal of magnetic resonance |
巻: | 213 |
号: | 1 |
開始ページ: | 192 |
終了ページ: | 195 |
抄録: | We present a new approach to nondestructive magic-angle spinning (MAS) nuclear magnetic resonance (NMR) for thin films. In this scheme, the sample put on the top of a rotor is spun using the conventional MAS system, and the NMR signals are detected with an additional coil. Stable spinning of disk-shaped samples with diameters of 7mm and 12mm at 14.2 and 7kHz are feasible. We present (7)Li MAS NMR experiments of a thin-film sample of LiCoO(2) with a thickness of 200nm. Taking advantage of the nondestructive feature of the experiment, we also demonstrate ex situ experiments, by tracing conformation change upon annealing for various durations. This approach opens the door for in situ MAS NMR of thin-film devices as well. |
著作権等: | © 2011 Elsevier Inc. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
URI: | http://hdl.handle.net/2433/150443 |
DOI(出版社版): | 10.1016/j.jmr.2011.09.013 |
PubMed ID: | 21958755 |
出現コレクション: | 学術雑誌掲載論文等 |
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