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Title: Preparation of 6-azafulleroid-6-deoxy-2,3-di-O-myristoylcellulose.
Authors: Ichihara, Nobuhiko
Takano, Toshiyuki  kyouindb  KAKEN_id
Sakakibara, Keita  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0002-6013-695X (unconfirmed)
Kamitakahara, Hiroshi  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0002-0130-1919 (unconfirmed)
Nakatsubo, Fumiaki
Author's alias: 高野, 俊幸
Keywords: Azafulleroid
Cellulose
Fullerene
Microwave heating
Issue Date: 8-Nov-2011
Publisher: Elsevier Ltd.
Journal title: Carbohydrate research
Volume: 346
Issue: 15
Start page: 2515
End page: 2518
Abstract: 6-Azafulleroid-6-deoxy-2, 3-di-O-myristoylcellulose (3) was synthesized from 6-azido-6-deoxycellulose (1) by two reaction steps. The myristoylation of compound 1 with myristoyl chloride/pyridine proceeded smoothly to give 6-azido-6-deoxy-2, 3-di-O-myristoylcellulose (2) in 97.0% yield. The reaction of compound 2 with fullerene (C_60) was carried out by microwave heating to afford compound 3 in high yield. It was found from FT-IR, [13]C NMR, UV-vis, differential pulse voltammetry (DPV), SEC analyses that compound 3 was the expected C_60-containing polymer. Consequently, maximum degree of substitution of C_60 (DS_{C60}) of compound 3 was 0.33.
Rights: © 2011 Elsevier Ltd.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
URI: http://hdl.handle.net/2433/151360
DOI(Published Version): 10.1016/j.carres.2011.08.013
PubMed ID: 21920512
Appears in Collections:Journal Articles

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