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| File | Description | Size | Format | |
|---|---|---|---|---|
| j.carres.2011.08.013.pdf | 321.17 kB | Adobe PDF | View/Open |
| Title: | Preparation of 6-azafulleroid-6-deoxy-2,3-di-O-myristoylcellulose. |
| Authors: | Ichihara, Nobuhiko Takano, Toshiyuki   Sakakibara, Keita  https://orcid.org/0000-0002-6013-695X (unconfirmed)Kamitakahara, Hiroshi https://orcid.org/0000-0002-0130-1919 (unconfirmed)Nakatsubo, Fumiaki |
| Author's alias: | 高野, 俊幸 |
| Keywords: | Azafulleroid Cellulose Fullerene Microwave heating |
| Issue Date: | 8-Nov-2011 |
| Publisher: | Elsevier Ltd. |
| Journal title: | Carbohydrate research |
| Volume: | 346 |
| Issue: | 15 |
| Start page: | 2515 |
| End page: | 2518 |
| Abstract: | 6-Azafulleroid-6-deoxy-2, 3-di-O-myristoylcellulose (3) was synthesized from 6-azido-6-deoxycellulose (1) by two reaction steps. The myristoylation of compound 1 with myristoyl chloride/pyridine proceeded smoothly to give 6-azido-6-deoxy-2, 3-di-O-myristoylcellulose (2) in 97.0% yield. The reaction of compound 2 with fullerene (C_60) was carried out by microwave heating to afford compound 3 in high yield. It was found from FT-IR, [13]C NMR, UV-vis, differential pulse voltammetry (DPV), SEC analyses that compound 3 was the expected C_60-containing polymer. Consequently, maximum degree of substitution of C_60 (DS_{C60}) of compound 3 was 0.33. |
| Rights: | © 2011 Elsevier Ltd. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/151360 |
| DOI(Published Version): | 10.1016/j.carres.2011.08.013 |
| PubMed ID: | 21920512 |
| Appears in Collections: | Journal Articles |
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