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Title: Rhodium-Catalyzed Carbene-Transfer Reactions via Thienylcarbene Complexes Generated from Thiocarbamoyl-ene-yne Compounds
Authors: Tsuneishi, Asuka
Okamoto, Kazuhiro  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0001-8562-3167 (unconfirmed)
Ikeda, Yuji
Murai, Masahito
Miki, Koji  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0002-4670-2302 (unconfirmed)
Ohe, Kouichi  kyouindb  KAKEN_id
Author's alias: 大江, 浩一
Keywords: thiocarbamoyl-ene-yne
rhodium
carbene complex
cyclopropanation
ring-opening reaction
Issue Date: Mar-2011
Publisher: Georg Thieme Verlag
Journal title: Synlett
Volume: 2011
Issue: 05
Start page: 655
End page: 658
Abstract: Catalytic thienylcarbene-transfer reactions have been developed. The rhodium-catalyzed reaction of alkenes, furans, and thiophenes with a thiocarbamoyl-ene-yne compound as a carbene source gave the cyclopropanation products or ring-opened products of heterocycles. These processes provide efficient synthetic methods for thiophene-containing complex molecules.
Rights: © Georg Thieme Verlag Stuttgart ˙ New York
この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。This is not the published version. Please cite only the published version.
URI: http://hdl.handle.net/2433/156437
DOI(Published Version): 10.1055/s-0030-1259559
Appears in Collections:Journal Articles

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