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Title: Itinerant electron magnetism of η-carbides Co6M6C and Ni6M6C (M=Mo and W)
Authors: Waki, T.  kyouindb  KAKEN_id
Furusawa, D.
Tabata, Y.  kyouindb  KAKEN_id
Michioka, C.  kyouindb  KAKEN_id
Yoshimura, K.
Kondo, A.
Kindo, K.
Nakamura, H.
Author's alias: 和氣, 剛
Keywords: Transition metal alloys and compounds
Solid state reaction
Electrical transport
Heat capacity
High magnetic fields
Magnetic measurements
Issue Date: Mar-2013
Publisher: Elsevier B.V.
Journal title: Journal of Alloys and Compounds
Volume: 554
Start page: 21
End page: 24
Abstract: Magnetic, transport, and thermal properties of metallic η-carbides Co6M6C and Ni6M6C (M = Mo and W) with the cubic Ni6Mo6C-type structure have been characterized. The Ni-based compounds Ni6Mo6C and Ni6W6C are Pauli paramagnets with temperature-independent susceptibilities. Susceptibilities of the Co-based compounds Co6Mo6C and Co6W6C are enhanced and temperature-dependent. Co6Mo6C remains paramagnetic down to the lowest temperature, while Co6W6C undergoes an antiferromagnetic-type transition at 46 K. A metamagnetic transition was observed for Co6W6C at 20–30 T at the lowest temperatures. The correlation among the enhancements in the susceptibility, the resistivity, and the electronic specific heat suggests the presence of moderate electron correlation in these compounds.
Rights: © 2012 Elsevier B.V.
この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。This is not the published version. Please cite only the published version.
DOI(Published Version): 10.1016/j.jallcom.2012.10.161
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