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タイトル: | Recent advances in transition-metal-catalyzed intermolecular carbomagnesiation and carbozincation |
著者: | Murakami, Kei Yorimitsu, Hideki https://orcid.org/0000-0002-0153-1888 (unconfirmed) |
著者名の別形: | 村上, 慧 依光, 英樹 |
キーワード: | alkene alkyne carbomagnesiation carbometalation carbozincation transition metal |
発行日: | 2013 |
出版者: | Beilstein-Institut |
誌名: | Beilstein Journal of Organic Chemistry |
巻: | 9 |
開始ページ: | 278 |
終了ページ: | 302 |
抄録: | Carbomagnesiation and carbozincation reactions are efficient and direct routes to prepare complex and stereodefined organomagnesium and organozinc reagents. However, carbon–carbon unsaturated bonds are generally unreactive toward organomagnesium and organozinc reagents. Thus, transition metals were employed to accomplish the carbometalation involving wide varieties of substrates and reagents. Recent advances of transition-metal-catalyzed carbomagnesiation and carbozincation reactions are reviewed in this article. The contents are separated into five sections: carbomagnesiation and carbozincation of (1) alkynes bearing an electron-withdrawing group; (2) alkynes bearing a directing group; (3) strained cyclopropenes; (4) unactivated alkynes or alkenes; and (5) substrates that have two carbon–carbon unsaturated bonds (allenes, dienes, enynes, or diynes). |
著作権等: | © 2013 Murakami and Yorimitsu; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (http://www.beilstein-journals.org/bjoc) |
URI: | http://hdl.handle.net/2433/172040 |
DOI(出版社版): | 10.3762/bjoc.9.34 |
PubMed ID: | 23503106 |
出現コレクション: | 学術雑誌掲載論文等 |
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