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タイトル: Liquid-phase synthesis and application of monolithic porous materials based on organic–inorganic hybrid methylsiloxanes, crosslinked polymers and carbons
著者: Kanamori, Kazuyoshi  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0001-5087-9808 (unconfirmed)
著者名の別形: 金森, 主祥
キーワード: Organic–inorganic hybrid
Aerogel and xerogel
Phase separation
Controlled/living radical polymerization
Crosslinked polymer
Activated carbon
発行日: Jan-2013
出版者: Springer US
誌名: Journal of Sol-Gel Science and Technology
巻: 65
号: 1
開始ページ: 12
終了ページ: 22
抄録: Our recent progress in porous materials based on organic–inorganic hybrids, organic crosslinked polymers, and carbons is summarized. Flexible aerogels and aerogel-like xerogels with the polymethylsilsesquioxane (PMSQ) composition are obtained using methyltrimethoxysilane (MTMS) as the sole precursor. Preparation process and the flexible mechanical properties of these aerogels/xerogels are overviewed. As the derivative materials, hierarchically macro- and mesoporous PMSQ monoliths and marshmallow-like soft and bendable porous monoliths prepared from dimethyldimethoxysilane /MTMS co-precursors have been obtained. Organic crosslinked polymer monoliths with well-defined macropores are also tailored using gelling systems of vinyl monomers under controlled/living radical polymerization. The obtained polymer monoliths are carbonized and activated into activated carbon monoliths with well-defined pore properties. The activated carbon monoliths exhibit good electrochemical properties as the monolithic electrode. Some possibilities of applications for these porous materials are also discussed.
著作権等: The final publication is available at www.springerlink.com
This is not the published version. Please cite only the published version.
この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
URI: http://hdl.handle.net/2433/172348
DOI(出版社版): 10.1007/s10971-011-2662-x
出現コレクション:学術雑誌掲載論文等

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