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タイトル: | Liquid-phase synthesis and application of monolithic porous materials based on organic–inorganic hybrid methylsiloxanes, crosslinked polymers and carbons |
著者: | Kanamori, Kazuyoshi ![]() ![]() ![]() |
著者名の別形: | 金森, 主祥 |
キーワード: | Organic–inorganic hybrid Aerogel and xerogel Phase separation Controlled/living radical polymerization Crosslinked polymer Activated carbon |
発行日: | Jan-2013 |
出版者: | Springer US |
誌名: | Journal of Sol-Gel Science and Technology |
巻: | 65 |
号: | 1 |
開始ページ: | 12 |
終了ページ: | 22 |
抄録: | Our recent progress in porous materials based on organic–inorganic hybrids, organic crosslinked polymers, and carbons is summarized. Flexible aerogels and aerogel-like xerogels with the polymethylsilsesquioxane (PMSQ) composition are obtained using methyltrimethoxysilane (MTMS) as the sole precursor. Preparation process and the flexible mechanical properties of these aerogels/xerogels are overviewed. As the derivative materials, hierarchically macro- and mesoporous PMSQ monoliths and marshmallow-like soft and bendable porous monoliths prepared from dimethyldimethoxysilane /MTMS co-precursors have been obtained. Organic crosslinked polymer monoliths with well-defined macropores are also tailored using gelling systems of vinyl monomers under controlled/living radical polymerization. The obtained polymer monoliths are carbonized and activated into activated carbon monoliths with well-defined pore properties. The activated carbon monoliths exhibit good electrochemical properties as the monolithic electrode. Some possibilities of applications for these porous materials are also discussed. |
著作権等: | The final publication is available at www.springerlink.com This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
URI: | http://hdl.handle.net/2433/172348 |
DOI(出版社版): | 10.1007/s10971-011-2662-x |
出現コレクション: | 学術雑誌掲載論文等 |

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