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タイトル: | Pressure-induced amorphization of a dense coordination polymer and its impact on proton conductivity |
著者: | Umeyama, Daiki Horike, Satoshi https://orcid.org/0000-0001-8530-6364 (unconfirmed) Tassel, Cedric https://orcid.org/0000-0002-8867-4813 (unconfirmed) Kageyama, Hiroshi Higo, Yuji Hagi, Keisuke Ogiwara, Naoki Kitagawa, Susumu https://orcid.org/0000-0001-6956-9543 (unconfirmed) |
著者名の別形: | 堀毛, 悟史 |
発行日: | 1-Dec-2014 |
出版者: | American Institute of Physics Inc. |
誌名: | APL Materials |
巻: | 2 |
号: | 12 |
開始ページ: | 124401 |
抄録: | The proton conductivity of a dense coordination polymer (CP) was investigated under high-pressure conditions. Impedance measurements under high pressures revealed that the proton conductivity of the CP decreased more than 1000-fold at pressures of 3–7 GPa and that the activation energy for proton conduction almost doubled compared with that at ambient pressure. A synchrotron X-ray study under high pressure identified the amorphization process of the CP during compression, which rationally explains the decrease in conductivity and increase in activation energy. This phenomenon is categorized as reversible pressure-induced amorphization of a dense CP and is regarded as a demonstration of the coupling of the mechanical and electrical properties of a CP. |
著作権等: | © 2014 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution 3.0 Unported License. |
URI: | http://hdl.handle.net/2433/191223 |
DOI(出版社版): | 10.1063/1.4898806 |
出現コレクション: | 学術雑誌掲載論文等 |
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