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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| 1.4903173.pdf | 2.28 MB | Adobe PDF | 見る/開く |
| タイトル: | Proton decoupling and recoupling under double-nutation irradiation in solid-state NMR. |
| 著者: | Takeda, Kazuyuki    https://orcid.org/0000-0002-6743-0932 (unconfirmed)Wakisaka, Asato Takegoshi, K https://orcid.org/0000-0002-4613-2987 (unconfirmed) |
| 著者名の別形: | 武田, 和行 |
| 発行日: | 14-Dec-2014 |
| 出版者: | American Institute of Physics |
| 誌名: | The Journal of chemical physics |
| 巻: | 141 |
| 号: | 22 |
| 論文番号: | 224202 |
| 抄録: | The effect of (1)H decoupling in magic-angle spinning solid-state NMR is studied under radiofrequency irradiation causing simultaneous nutations around a pair of orthogonal axes. Double-nutation with an arbitrary pair of nutation frequencies is implemented through modulation of the amplitude, phase, and frequency of the transmitting pulses. Similarity and difference of double-nutation decoupling and two-pulse phase-modulation decoupling schemes [A. E. Bennett, C. M. Rienstra, M. Auger, K. V. Lakshmi, and R. G. Griffin, J. Chem. Phys. 103, 6951-6958 (1995) and I. Scholz, P. Hodgkinson, B. H. Meier, and M. Ernst, J. Chem. Phys. 130, 114510 (2009)] are discussed. The structure of recoupling bands caused by interference of the (1)H spin nutation with sample spinning is studied by both experiments and numerical simulations. |
| 著作権等: | Copyright 2014 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics |
| URI: | http://hdl.handle.net/2433/193245 |
| DOI(出版社版): | 10.1063/1.4903173 |
| PubMed ID: | 25494742 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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