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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| cl.2013.222.pdf | 758.64 kB | Adobe PDF | 見る/開く |
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| DCフィールド | 値 | 言語 |
|---|---|---|
| dc.contributor.author | Uemura, Takashi | en |
| dc.contributor.author | Washino, Gosuke | en |
| dc.contributor.author | Yanai, Nobuhiro | en |
| dc.contributor.author | Kitagawa, Susumu | en |
| dc.date.accessioned | 2015-02-18T06:09:56Z | - |
| dc.date.available | 2015-02-18T06:09:56Z | - |
| dc.date.issued | 2013-03-05 | - |
| dc.identifier.issn | 0366-7022 | - |
| dc.identifier.uri | http://hdl.handle.net/2433/193759 | - |
| dc.description.abstract | A photoresponsive controlled adsorption system based on a porous coordination polymer (PCP) was fabricated, using azobenzene tethered with poly(ethylene glycol) (PEG-AB) as macromolecular guests. Specific adsorption behavior of trans-PEG-AB into the nanochannels of a PCP was observed in an EtOH medium. When this composite was irradiated with UV light in EtOH, isomerization of PEG-AB from the trans to the cis form resulted in release of PEG-AB because of the large changes in the molecular shape and solubility of PEG-AB. Subsequent visible light irradiation induced photoisomerization of PEG-AB, which led to readsorption of PEG-AB into the nanochannels. | en |
| dc.format.mimetype | application/pdf | - |
| dc.language.iso | eng | - |
| dc.publisher | Chemical Society of Japan | en |
| dc.publisher.alternative | 日本化学会 | ja |
| dc.rights | © 2013 The Chemical Society of Japan | en |
| dc.title | Controlled Encapsulation of Photoresponsive Macromolecules in Porous Coordination Polymer | en |
| dc.type | journal article | - |
| dc.type.niitype | Journal Article | - |
| dc.identifier.ncid | AA00603318 | - |
| dc.identifier.jtitle | Chemistry Letters | en |
| dc.identifier.volume | 42 | - |
| dc.identifier.issue | 3 | - |
| dc.identifier.spage | 222 | - |
| dc.identifier.epage | 223 | - |
| dc.relation.doi | 10.1246/cl.2013.222 | - |
| dc.textversion | publisher | - |
| dcterms.accessRights | open access | - |
| 出現コレクション: | 学術雑誌掲載論文等 | |
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