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タイトル: | The Synthesis of Alkaloids Using Transition-Metal-Catalyzed Intramolecular Amination Reactions |
著者: | Ohno, Hiroaki https://orcid.org/0000-0002-3246-4809 (unconfirmed) Chiba, Hiroaki Inuki, Shinsuke https://orcid.org/0000-0002-7525-1280 (unconfirmed) Oishi, Shinya https://orcid.org/0000-0002-2833-2539 (unconfirmed) Fujii, Nobutaka |
著者名の別形: | 大野, 浩章 |
キーワード: | total synthesis palladium gold alkaloids atom economy |
発行日: | 13-Jan-2014 |
出版者: | Georg Thieme Verlag KG |
誌名: | Synlett |
巻: | 25 |
号: | 02 |
開始ページ: | 179 |
終了ページ: | 192 |
抄録: | Transition-metal-catalyzed reactions have the potential to provide significant improvements to the syntheses of complex target molecules. These reactions can be used to achieve a variety of different atom-economical transformations and cascade reactions and, therefore, provide access to synthetic strategies that would otherwise be unavailable using classical organic chemistry. To exemplify the utility of the latest transition-metal-catalyzed reactions for the construction of important target structures, we have been involved in the total synthesis of natural products bearing widely known chemical scaffolds. In this account, we report our recent studies on the use of a palladium-catalyzed cascade cyclization reaction and a gold(I)-catalyzed hydroamination reaction for the construction of the core structures of alkaloids, as well as their application to the total syntheses of lysergic acid, lysergol, isolysergol, and quinocarcin. |
著作権等: | © Georg Thieme Verlag Stuttgart · New York この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
URI: | http://hdl.handle.net/2433/196783 |
DOI(出版社版): | 10.1055/s-0033-1340165 |
出現コレクション: | 学術雑誌掲載論文等 |
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