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Title: Formal [4+2] reaction between 1,3-diynes and pyrroles: gold(I)-catalyzed indole synthesis by double hydroarylation.
Authors: Matsuda, Yuka
Naoe, Saori
Oishi, Shinya
Fujii, Nobutaka
Ohno, Hiroaki
Author's alias: 藤井, 信孝
大野, 浩章
Keywords: carbazoles
cascade reaction
gold catalysis
hydroarylation
indoles
Issue Date: 28-Nov-2014
Publisher: wiley
Journal title: Chemistry : A European Journal
Volume: 21
Issue: 4
Start page: 1463
End page: 1467
Abstract: Indole synthesis by a gold(I)-catalyzed intermolecular formal [4+2] reaction between 1,3-diynes and pyrroles has been developed. This reaction involves the hydroarylation of 1,3-diynes with pyrroles followed by an intramolecular hydroarylation to give the 4,7-disubstituted indoles. This reaction can also be applied to the synthesis of carbazoles when indoles are used as the nucleophiles instead of pyrroles.
Rights: This is the peer reviewed version of the following article: Matsuda, Y., Naoe, S., Oishi, S., Fujii, N. and Ohno, H. (2015), Formal [4+2] Reaction between 1,3-Diynes and Pyrroles: Gold(I)-Catalyzed Indole Synthesis by Double Hydroarylation. Chem. Eur. J., 21: 1463-1467, which has been published in final form at http://dx.doi.org/10.1002/chem.201405903. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
許諾条件により本文ファイルは2015-11-28に公開.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
URI: http://hdl.handle.net/2433/198281
DOI(Published Version): 10.1002/chem.201405903
PubMed ID: 25447042
Appears in Collections:Journal Articles

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