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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| anie.201404355.pdf | 310.77 kB | Adobe PDF | 見る/開く |
| タイトル: | Palladium-catalyzed amination of aryl sulfides with anilines. |
| 著者: | Sugahara, Tomohiro Murakami, Kei Yorimitsu, Hideki    https://orcid.org/0000-0002-0153-1888 (unconfirmed)Osuka, Atsuhiro |
| 著者名の別形: | 依光, 英樹 |
| キーワード: | amination aryl sulfides N-heterocyclic carbene ligands palladium Pummerer reaction |
| 発行日: | 7-Jul-2014 |
| 出版者: | wiley |
| 誌名: | Angewandte Chemie - International Edition |
| 巻: | 53 |
| 号: | 35 |
| 開始ページ: | 9329 |
| 終了ページ: | 9333 |
| 抄録: | A combination of a palladium-NHC catalyst and potassium hexamethyldisilazide enables the amination of aryl sulfides with anilines to afford a wide variety of diarylamines. The reaction conditions are versatile enough for the reaction of even bulky ortho-substituted aryl sulfides. This amination can be applied to the modular synthesis of N-aryl carbazoles from the corresponding ortho-bromothioanisoles. As aryl sulfoxides undergo extended Pummerer reactions to afford ortho-substituted aryl sulfides, the Pummerer products are thus useful substrates for the amination to culminate in efficient syntheses of a 2-anilinobenzothiophene and an indole as proof-of-principle of the utility of the extended Pummerer reaction/amination cascade. |
| 著作権等: | This is the peer reviewed version of the following article: Sugahara, T., Murakami, K., Yorimitsu, H. and Osuka, A. (2014), Palladium-Catalyzed Amination of Aryl Sulfides with Anilines. Angew. Chem. Int. Ed., 53: 9329–9333, which has been published in final form at http://dx.doi.org/10.1002/anie.201404355. 許諾条件により本文ファイルは2015-07-07に公開. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
| URI: | http://hdl.handle.net/2433/198446 |
| DOI(出版社版): | 10.1002/anie.201404355 |
| PubMed ID: | 25044919 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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