このアイテムのアクセス数: 427
このアイテムのファイル:
| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| chem.201404380.pdf | 272.55 kB | Adobe PDF | 見る/開く |
| タイトル: | Palladium-catalyzed cross-coupling of unactivated aryl sulfides with arylzinc reagents under mild conditions. |
| 著者: | Otsuka, Shinya Fujino, Daishi Murakami, Kei Yorimitsu, Hideki    https://orcid.org/0000-0002-0153-1888 (unconfirmed)Osuka, Atsuhiro |
| 著者名の別形: | 依光, 英樹 |
| キーワード: | cross-coupling C[BOND]S bond activation organosulfur compounds organozinc compounds palladium |
| 発行日: | 28-Aug-2014 |
| 出版者: | wiley |
| 誌名: | Chemistry - A European Journal |
| 巻: | 20 |
| 号: | 41 |
| 開始ページ: | 13146 |
| 終了ページ: | 13149 |
| 抄録: | Cross-coupling of general aryl alkyl sulfides with arylzinc reagents proceeds smoothly, even at room temperature or below, with a palladium-N-heterocyclic carbene (NHC) catalyst. When combined with reactions that are unique to organosulfurs, that is, the SNAr sulfanylation or Pummerer reaction, the cross-coupling offers interesting transformations that are otherwise difficult to achieve. An alkylsulfanyl group is preferentially converted whilst leaving the tosyloxy and chloro intact, which expands the variety of orthogonal cross-coupling. |
| 著作権等: | This is the peer reviewed version of the following article: Otsuka, S., Fujino, D., Murakami, K., Yorimitsu, H. and Osuka, A. (2014), Palladium-Catalyzed Cross-Coupling of Unactivated Aryl Sulfides with Arylzinc Reagents under Mild Conditions. Chem. Eur. J., 20: 13146–13149, which has been published in final form at http://dx.doi.org/10.1002/chem.201404380
. 許諾条件により本文ファイルは2015-08-28に公開. / This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/198447 |
| DOI(出版社版): | 10.1002/chem.201404380 |
| PubMed ID: | 25168477 |
| 出現コレクション: | 学術雑誌掲載論文等 |
このリポジトリに保管されているアイテムはすべて著作権により保護されています。