|Title:||Hydrostannylation-Cross-Coupling Strategy for the Stereoselective Synthesis of Alkylidenemalonates and Related α,β-Unsaturated Esters|
Takasu, Kiyosei https://orcid.org/0000-0002-1798-7919 (unconfirmed)
|Author's alias:||山田, 健一|
|Journal title:||European Journal of Organic Chemistry|
|Abstract:||A method for the stereoselective synthesis of alkylidenemalonates and related α, β-unsaturated esters by a hydrostannylation–cross-coupling process has been developed. Pd-catalyzed and radical hydrostannylation of propiolate derivatives stereoselectively provided α-alkoxycarbonyl (E)- and (Z)-vinylstannanes, respectively, which were then converted into alkylidenemalonates by the Stille coupling reaction. A one-pot process was also realizable for the Pd-catalyzed reactions.|
|Rights:||This is the peer reviewed version of the following article: Fujiwara, S., Cadou, R., Yamaoka, Y., Takasu, K. and Yamada, K.-i. (2015), Hydrostannylation–Cross-Coupling Strategy for the Stereoselective Synthesis of Alkylidenemalonates and Related α, β-Unsaturated Esters. Eur. J. Org. Chem., 2015: 1264–1272, which has been published in final form at http://dx.doi.org/10.1002/ejoc.201403429. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.|
This is not the published version. Please cite only the published version.
|Appears in Collections:||Journal Articles|
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