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タイトル: On-top π-stacking of quasiplanar molecules in hole-transporting materials: inducing anisotropic carrier mobility in amorphous films.
著者: Wakamiya, Atsushi  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0003-1430-0947 (unconfirmed)
Nishimura, Hidetaka
Fukushima, Tatsuya
Suzuki, Furitsu
Saeki, Akinori
Seki, Shu  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0001-7851-4405 (unconfirmed)
Osaka, Itaru
Sasamori, Takahiro
Murata, Michihisa
Murata, Yasujiro  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0003-0287-0299 (unconfirmed)
Kaji, Hironori  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0002-5111-3852 (unconfirmed)
著者名の別形: 若宮, 淳志
キーワード: amorphous materials
heterocycles
semiconductors
structure–function relationships
structure elucidation
発行日: 2-Jun-2014
出版者: wiley
誌名: Angewandte Chemie
巻: 53
号: 23
開始ページ: 5800
終了ページ: 5804
抄録: Dimers of partially oxygen-bridged triarylamines were designed and synthesized as hole-transporting materials. X-ray structural analyses revealed that these compounds form on-top π-stacking aggregates in the crystalline state. TRMC measurements showed that high levels of anisotropic charge transport were induced in the direction of the π-stacking. Surprisingly, even in vacuum-deposited amorphous films, these compounds retained some of the face-on π-stacking, thus facilitating an out-of-plane carrier mobility.
著作権等: This is the peer reviewed version of the following article: Murata, M., Murata, Y. and Kaji, H. (2014), On-Top π-Stacking of Quasiplanar Molecules in Hole-Transporting Materials: Inducing Anisotropic Carrier Mobility in Amorphous Films. Angew. Chem. Int. Ed., 53: 5800–5804, which has been published in final form at http://dx.doi.org/10.1002/anie.201400068. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
This is not the published version. Please cite only the published version.
この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
URI: http://hdl.handle.net/2433/199585
DOI(出版社版): 10.1002/anie.201400068
PubMed ID: 24764307
出現コレクション:学術雑誌掲載論文等

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