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タイトル: | On-top π-stacking of quasiplanar molecules in hole-transporting materials: inducing anisotropic carrier mobility in amorphous films. |
著者: | Wakamiya, Atsushi ![]() ![]() ![]() Nishimura, Hidetaka Fukushima, Tatsuya Suzuki, Furitsu Saeki, Akinori Seki, Shu ![]() ![]() ![]() Osaka, Itaru Sasamori, Takahiro Murata, Michihisa Murata, Yasujiro ![]() ![]() ![]() Kaji, Hironori ![]() ![]() ![]() |
著者名の別形: | 若宮, 淳志 |
キーワード: | amorphous materials heterocycles semiconductors structure–function relationships structure elucidation |
発行日: | 2-Jun-2014 |
出版者: | wiley |
誌名: | Angewandte Chemie |
巻: | 53 |
号: | 23 |
開始ページ: | 5800 |
終了ページ: | 5804 |
抄録: | Dimers of partially oxygen-bridged triarylamines were designed and synthesized as hole-transporting materials. X-ray structural analyses revealed that these compounds form on-top π-stacking aggregates in the crystalline state. TRMC measurements showed that high levels of anisotropic charge transport were induced in the direction of the π-stacking. Surprisingly, even in vacuum-deposited amorphous films, these compounds retained some of the face-on π-stacking, thus facilitating an out-of-plane carrier mobility. |
著作権等: | This is the peer reviewed version of the following article: Murata, M., Murata, Y. and Kaji, H. (2014), On-Top π-Stacking of Quasiplanar Molecules in Hole-Transporting Materials: Inducing Anisotropic Carrier Mobility in Amorphous Films. Angew. Chem. Int. Ed., 53: 5800–5804, which has been published in final form at http://dx.doi.org/10.1002/anie.201400068. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
URI: | http://hdl.handle.net/2433/199585 |
DOI(出版社版): | 10.1002/anie.201400068 |
PubMed ID: | 24764307 |
出現コレクション: | 学術雑誌掲載論文等 |

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