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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| ejoc.201402391.pdf | 309 kB | Adobe PDF | 見る/開く |
| タイトル: | Efficient Synthesis and Versatile Reactivity of Porphyrinyl Grignard Reagents |
| 著者: | Fujimoto, Keisuke Yorimitsu, Hideki    https://orcid.org/0000-0002-0153-1888 (unconfirmed)Osuka, Atsuhiro |
| 著者名の別形: | 依光, 英樹 |
| キーワード: | Porphyrinoids Iodine–magnesium exchange Grignard reaction Metalation |
| 発行日: | 22-May-2014 |
| 出版者: | wiley |
| 誌名: | European Journal of Organic Chemistry |
| 巻: | 2014 |
| 号: | 20 |
| 開始ページ: | 4327 |
| 終了ページ: | 4334 |
| 抄録: | Iodine–magnesium exchange between iodoporphyrins and iPrMgCl·LiCl proceeded successfully without decomposition of the porphyrin core. The resulting porphyrinyl Grignard reagents are nucleophilic enough to react with various carbonyl compounds, such as aldehydes, ketones, and amides. Furthermore, the porphyrinyl Grignard reagents underwent transmetalation to afford porphyrinyl copper and zinc species of mild and unique reactivity. These could be engaged in 1, 4-addition and Negishi coupling, respectively. |
| 著作権等: | This is the peer reviewed version of the following article: Fujimoto, K., Yorimitsu, H. and Osuka, A. (2014), Efficient Synthesis and Versatile Reactivity of Porphyrinyl Grignard Reagents. Eur. J. Org. Chem., 2014: 4327–4334, which has been published in final form at http://dx.doi.org/10.1002/ejoc.201402391. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
| URI: | http://hdl.handle.net/2433/200176 |
| DOI(出版社版): | 10.1002/ejoc.201402391 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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