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Title: N-Heterocyclic Carbene-Catalyzed Benzoin Strategy for Divergent Synthesis of Cyclitol Derivatives from Alditols
Authors: Kang, Bubwoong
Sutou, Toshiaki
Wang, Yinli
Kuwano, Satoru
Yamaoka, Yousuke
Takasu, Kiyosei  kyouindb  KAKEN_id  orcid (unconfirmed)
Yamada, Ken-ichi
Author's alias: 高須, 清誠
山田, 健一
Keywords: benzoin reaction
cyclitol derivatives
N-heterocyclic carbenes
Issue Date: 8-Dec-2014
Publisher: Wiley
Journal title: Advanced Synthesis & Catalysis
Volume: 357
Issue: 1
Start page: 131
End page: 147
Abstract: A divergent synthesis of cyclitol derivatives has been developed utilizing an N-heterocyclic carbene-catalyzed benzoin-type cyclization of C2-symmetrical dialdoses. The resulting inososes are versatile intermediates, which are readily converted into not only inositols but also amino-, deoxy-, O-methyl- and C-methyl-inositols.
Rights: This is the peer reviewed version of the following article: Kang, B., Sutou, T., Wang, Y., Kuwano, S., Yamaoka, Y., Takasu, K. and Yamada, K.-i. (2015), N-Heterocyclic Carbene-Catalyzed Benzoin Strategy for Divergent Synthesis of Cyclitol Derivatives from Alditols. Adv. Synth. Catal., 357: 131–147, which has been published in final form at This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
The full-text file will be made open to the public on 8 DEC 2015 in accordance with publisher's 'Terms and Conditions for Self-Archiving'
This is not the published version. Please cite only the published version.
DOI(Published Version): 10.1002/adsc.201400712
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