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| Title: | Order-to-disorder structural transformation of a coordination polymer and its influence on proton conduction. |
| Authors: | Horike, Satoshi    https://orcid.org/0000-0001-8530-6364 (unconfirmed)Chen, Wenqian Itakura, Tomoya Inukai, Munehiro Umeyama, Daiki Asakura, Hiroyuki https://orcid.org/0000-0001-6451-4738 (unconfirmed)Kitagawa, Susumu https://orcid.org/0000-0001-6956-9543 (unconfirmed) |
| Author's alias: | 堀毛, 悟史 |
| Issue Date: | 16-Jul-2014 |
| Publisher: | Royal Society of Chemistry |
| Journal title: | Chemical communications |
| Volume: | 50 |
| Issue: | 71 |
| Start page: | 10241 |
| End page: | 10243 |
| Abstract: | We observed an ordered-to-disordered structural transformation in a Cu(2+) coordination polymer and investigated its influence on the proton conductivity. The transformation generated highly mobile proton carriers in the structure. The resulting material exhibited a conductivity greater than 10(-2) S cm(-1) at 130 °C. The structural transformation and the conduction mechanism were investigated by EXAFS, TPD-MS and NMR. |
| Description: | Accepted 14 Jul 2014. |
| Rights: | This journal is © The Royal Society of Chemistry 2014. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/200183 |
| DOI(Published Version): | 10.1039/c4cc04370g |
| PubMed ID: | 25053211 |
| Appears in Collections: | Journal Articles |
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