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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| masy.201400027.pdf | 1.24 MB | Adobe PDF | 見る/開く |
| タイトル: | Synthesis of Amphiphilic Three-Armed Star Random Copolymers via Living Radical Polymerization and their Unimolecular Folding Properties in Water |
| 著者: | Sugita, Takanori Matsumoto, Kazuma Terashima, Takaya    https://orcid.org/0000-0002-9917-8049 (unconfirmed)Sawamoto, Mitsuo |
| 著者名の別形: | 寺島, 崇矢 |
| キーワード: | amphiphilic copolymer folding hydrophobic interaction living radical polymerization star polymer unimer micelle |
| 発行日: | 2-Apr-2015 |
| 出版者: | wiley |
| 誌名: | Macromolecular Symposia |
| 巻: | 350 |
| 号: | 1 |
| 開始ページ: | 76 |
| 終了ページ: | 85 |
| 抄録: | Amphiphilic three-armed star random copolymers were synthesized by ruthenium-catalyzed living radical copolymerization of hydrophilic poly(ethylene glycol) methyl ether methacrylate (PEGMA) and hydrophobic dodecyl methacrylate (DMA). Their amphiphilic star random copolymers with 10-50 mol% DMA efficiently self-folded in water with intramolecular hydrophobic interaction to form compact unimolecular micelles. Owing to PEG segments, star copolymers were thermoresponsive to induce lower critical solution temperature-type phase separation in water. |
| 著作権等: | This is the peer reviewed version of the following article: Sugita, T., Matsumoto, K., Terashima, T. and Sawamoto, M. (2015), Synthesis of Amphiphilic Three-Armed Star Random Copolymers via Living Radical Polymerization and their Unimolecular Folding Properties in Water. Macromol. Symp., 350: 76–85, which has been published in final form at http://dx.doi.org/10.1002/masy.201400027. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. The full-text file will be made open to the public on 2 APR 2016 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/200748 |
| DOI(出版社版): | 10.1002/masy.201400027 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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