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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| marc.201500104.pdf | 859.02 kB | Adobe PDF | 見る/開く |
| タイトル: | Synthesis of a platinum diketonate-containing polymer showing oxygen-resistant phosphorescence. |
| 著者: | Tanaka, Kazuo    https://orcid.org/0000-0001-6571-7086 (unconfirmed)Hirose, Amane Tamashima, Kenji Chujo, Yoshiki |
| 著者名の別形: | 田中, 一生 中條, 善樹 |
| キーワード: | platinum complexes diketonate oxygen conjugated polymers |
| 発行日: | 3-Mar-2015 |
| 出版者: | wiley |
| 誌名: | Macromolecular rapid communications |
| 巻: | 36 |
| 号: | 7 |
| 開始ページ: | 684 |
| 終了ページ: | 688 |
| 抄録: | The synthesis of a platinum diketonate-based alternating copolymer containing a fluorene unit and its oxygen-resistant phosphorescence are reported. The polymerization is executed via palladium-catalyzed Suzuki-Miyaura coupling reaction. The synthesized polymer shows good solubility in common organic solvents and processability to form homogeneous films. By optical measurements it is found that the synthesized polymer shows phosphorescence from a triplet π-π* ligand-centered transition, and interestingly, the emission is hardly influenced by oxygen. Phosphorescence is observed from both solution and film samples under aerobic conditions. The new idea of obtaining emissive materials based on conjugated polymers showing oxygen-resistant phosphorescence is presented here. |
| 著作権等: | This is the peer reviewed version of the following article: Tanaka, K., Hirose, A., Tamashima, K. and Chujo, Y. (2015), Synthesis of a Platinum Diketonate-Containing Polymer Showing Oxygen-Resistant Phosphorescence. Macromol. Rapid Commun., 36: 684–688, which has been published in final form at http://dx.doi.org/10.1002/marc.201500104. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. The full-text file will be made open to the public on 3 MAR 2016 in accordance with publisher's 'Terms and Conditions for Self-Archiving' この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
| URI: | http://hdl.handle.net/2433/200781 |
| DOI(出版社版): | 10.1002/marc.201500104 |
| PubMed ID: | 25737390 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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