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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| j.tet.2015.01.066.pdf | 358.94 kB | Adobe PDF | 見る/開く |
| タイトル: | Palladium-catalyzed formal hydroacylation of allenes employing carboxylic anhydrides and hydrosilanes |
| 著者: | Fujihara, Tetsuaki    https://orcid.org/0000-0002-6687-2528 (unconfirmed)Hosomi, Takuro Cong, Cong Hosoki, Tomoya Terao, Jun Tsuji, Yasushi |
| 著者名の別形: | 藤原, 哲晶 |
| キーワード: | Allene Carboxylic anhydride Hydroacylation Hydrosilane Palladium |
| 発行日: | 1-Jul-2015 |
| 出版者: | Elsevier Ltd. |
| 誌名: | Tetrahedron |
| 巻: | 71 |
| 号: | 26-27 |
| 開始ページ: | 4570 |
| 終了ページ: | 4574 |
| 抄録: | The formal hydroacylation reaction of allenes has been developed employing carboxylic anhydrides as acyl sources and hydrosilanes as reducing reagents in the presence of a commercially available palladium complex as a catalyst. The reaction affords α, β-unsaturated ketones regio- and stereoselectively. The similar catalyst system is also effective for the reduction of carboxylic anhydrides to the corresponding aldehydes employing hydrosilanes. |
| 著作権等: | © 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ The full-text file will be made open to the public on 01 July 2017 in accordance with publisher's 'Terms and Conditions for Self-Archiving' This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/201514 |
| DOI(出版社版): | 10.1016/j.tet.2015.01.066 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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