ダウンロード数: 241
このアイテムのファイル:
| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| chem.201501822.pdf | 5.08 MB | Adobe PDF | 見る/開く |
| タイトル: | Hybrid [5]Radialenes with Bispyrroloheteroles: New Electron-Donating Units. |
| 著者: | Higashino, Tomohiro    https://orcid.org/0000-0002-9531-8569 (unconfirmed)Imahori, Hiroshi |
| 著者名の別形: | 今堀, 博 |
| キーワード: | charge transfer donor–acceptor systems heterocycles UV/Vis spectroscopy X-ray diffraction |
| 発行日: | 4-Aug-2015 |
| 出版者: | wiley |
| 誌名: | Chemistry - A European Journal |
| 巻: | 21 |
| 号: | 38 |
| 開始ページ: | 13375 |
| 終了ページ: | 13381 |
| 抄録: | Bispyrroloheteroles have been synthesized to address their intrinsic structural, optical, and electrochemical properties. The X-ray crystal structures and calculated natural bond orbital (NBO) bond orders unambiguously demonstrated the existence of a two pyrrole-fused five-membered ring with short exocyclic C-C double bonds and long endocyclic C-C single bonds, supporting that the bispyrroloheteroles are rare examples of structurally characterized hybrid [5]radialenes. The bispyrroloheteroles were found to act as an electron-donating unit, which would be fascinating for the rational design of new charge-transporting and donor-acceptor photovoltaic materials as well as versatile charge-transfer complexes. |
| 著作権等: | This is the peer reviewed version of the following article: Higashino, T. and Imahori, H. (2015), Hybrid [5]Radialenes with Bispyrroloheteroles: New Electron-Donating Units. Chem. Eur. J., 21: 13375–13381, which has been published in final form at http://dx.doi.org/10.1002/chem.201501822. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. The full-text file will be made open to the public on 4 August 2016in accordance with publisher's 'Terms and Conditions for Self-Archiving'. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
| URI: | http://hdl.handle.net/2433/201853 |
| DOI(出版社版): | 10.1002/chem.201501822 |
| PubMed ID: | 26242481 |
| 出現コレクション: | 学術雑誌掲載論文等 |
このリポジトリに保管されているアイテムはすべて著作権により保護されています。