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j.tet.2015.03.014.pdf767.97 kBAdobe PDF見る/開く
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dc.contributor.authorNishimura, Katsumien
dc.contributor.authorFukuyama, Naoshien
dc.contributor.authorYasuhara, Tomohisaen
dc.contributor.authorYamashita, Mitsuakien
dc.contributor.authorSumiyoshi, Takaakien
dc.contributor.authorYamamoto, Yasutomoen
dc.contributor.authorYamada, Ken-ichien
dc.contributor.authorTomioka, Kiyoshien
dc.contributor.alternative山田, 健一ja
dc.contributor.alternative富岡, 清ja
dc.date.accessioned2015-11-24T02:50:44Z-
dc.date.available2015-11-24T02:50:44Z-
dc.date.issued2015-09-30-
dc.identifier.issn0040-4020-
dc.identifier.urihttp://hdl.handle.net/2433/201854-
dc.description.abstractThe chiral diether ligand-controlled asymmetric conjugate addition of organolithiums to nona-2, 7-dienedioate and subsequent intramolecular conjugate addition of the enolate intermediate gave all-trans trisubstituted cyclohexanes with high ee and yields. Using this methodology, an efficient short asymmetric total synthesis of (+)-β-lycorane was accomplished in 33% overall yield through five steps from the dienedioate.en
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherElsevier Ltd.en
dc.rights© 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.rightsThe full-text file will be made open to the public on 30 September 2017 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.en
dc.rightsこの論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。ja
dc.rightsThis is not the published version. Please cite only the published version.en
dc.subjectChiral liganden
dc.subjectAsymmetric synthesisen
dc.subjectOrganolithiumsen
dc.subjectConjugate additionen
dc.subjectLycoraneen
dc.titleA short synthesis of (+)-β-lycorane by asymmetric conjugate addition cascadeen
dc.typejournal article-
dc.type.niitypeJournal Article-
dc.identifier.ncidAA00861787-
dc.identifier.jtitleTetrahedronen
dc.identifier.volume71-
dc.identifier.issue39-
dc.identifier.spage7222-
dc.identifier.epage7226-
dc.relation.doi10.1016/j.tet.2015.03.014-
dc.textversionauthor-
dc.startdate.bitstreamsavailable2017-09-30-
dcterms.accessRightsopen access-
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