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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| c5ra08584e.pdf | 965.05 kB | Adobe PDF | 見る/開く |
| タイトル: | High HOMO levels and narrow energy band gaps of dithienogalloles |
| 著者: | Matsumoto, Takuya Tanaka, Kazuo    https://orcid.org/0000-0001-6571-7086 (unconfirmed)Chujo, Yoshiki |
| 著者名の別形: | 田中, 一生 中條, 善樹 |
| 発行日: | 24-Jun-2015 |
| 出版者: | Royal Society of Chemistry |
| 誌名: | RSC Advances |
| 巻: | 5 |
| 号: | 68 |
| 開始ページ: | 55406 |
| 終了ページ: | 55410 |
| 抄録: | We synthesized dithieno[3, 2-b:2′, 3′-d]galloles containing four-coordinated gallium atoms. It was found that dithienogalloles had high stability to air and moisture and showed narrower energy-band gaps than dithienosiloles which are commodity materials in organic opto and/or electronic devices. In addition, relatively-higher HOMO levels were observed from dithienogalloles than those of other dithienoheteroles from electrochemical measurements. We experimentally and theoretically demonstrated the electron-donating properties and resonance effects of gallium atoms of dithienogalloles. |
| 著作権等: | This journal is © The Royal Society of Chemistry 2015. The full-text file will be made open to the public on 19 June 2016 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
| URI: | http://hdl.handle.net/2433/201947 |
| DOI(出版社版): | 10.1039/C5RA08584E |
| 出現コレクション: | 学術雑誌掲載論文等 |
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