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dc.contributor.authorHigashino, Tomohiroen
dc.contributor.authorFujimori, Yamatoen
dc.contributor.authorSugiura, Kenichien
dc.contributor.authorTsuji, Yukihiroen
dc.contributor.authorIto, Seigoen
dc.contributor.authorImahori, Hiroshien
dc.contributor.alternative今堀, 博ja
dc.date.accessioned2015-12-01T01:58:52Z-
dc.date.available2015-12-01T01:58:52Z-
dc.date.issued2015-07-27-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/2433/202019-
dc.descriptionArticle first published online: 16 JUN 2015en
dc.description.abstractA tropolone group has been employed for the first time as an anchoring group for dye-sensitized solar cells (DSSCs). The DSSC based on a porphyrin, YD2-o-C8T, with a tropolone moiety exhibited a power-conversion efficiency of 7.7 %, which is only slightly lower than that observed for a reference porphyrin, YD2-o-C8, with a conventional carboxylic group. More importantly, YD2-o-C8T was found to be superior to YD2-o-C8 with respect to DSSC durability and binding ability to TiO2 . These results unambiguously demonstrate that tropolone is a highly promising dye-anchoring group for DSSCs in terms of device durability as well as photovoltaic performance.en
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherwileyen
dc.rightsThis is the peer reviewed version of the following article: Higashino, T., Fujimori, Y., Sugiura, K., Tsuji, Y., Ito, S. and Imahori, H. (2015), Tropolone as a High-Performance Robust Anchoring Group for Dye-Sensitized Solar Cells. Angew. Chem. Int. Ed., 54: 9052–9056, which has been published in final form at http://dx.doi.org/10.1002/anie.201502951. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.en
dc.rightsThe full-text file will be made open to the public on 16 June 2016 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.en
dc.rightsThis is not the published version. Please cite only the published version.en
dc.rightsこの論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。ja
dc.subjectanchoring groupsen
dc.subjectlight harvestingen
dc.subjectporphyrinoidsen
dc.subjectsensitizersen
dc.subjectsolar cellsen
dc.titleTropolone as a High-Performance Robust Anchoring Group for Dye-Sensitized Solar Cells.en
dc.typejournal article-
dc.type.niitypeJournal Article-
dc.identifier.ncidAA0052535X-
dc.identifier.jtitleAngewandte Chemieen
dc.identifier.volume54-
dc.identifier.issue31-
dc.identifier.spage9052-
dc.identifier.epage9056-
dc.relation.doi10.1002/anie.201502951-
dc.textversionauthor-
dc.startdate.bitstreamsavailable2016-06-16-
dc.identifier.pmid26080034-
dcterms.accessRightsopen access-
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