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Title: Mesoscopic superstructures of flexible porous coordination polymers synthesized via coordination replication
Authors: Sumida, Kenji
Moitra, Nirmalya
Reboul, Julien
Fukumoto, Shotaro
Nakanishi, Kazuki  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0002-8069-4780 (unconfirmed)
Kanamori, Kazuyoshi  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0001-5087-9808 (unconfirmed)
Furukawa, Shuhei  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0003-3849-8038 (unconfirmed)
Kitagawa, Susumu  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0001-6956-9543 (unconfirmed)
Author's alias: 古川, 修平
北川, 進
Issue Date: 29-Jun-2015
Publisher: Royal Society of Chemistry
Journal title: Chemical Science
Volume: 6
Start page: 5938
End page: 5946
Abstract: The coordination replication technique is employed for the direct conversion of a macro- and mesoporous Cu(OH)<inf>2</inf>-polyacrylamide composite to three-dimensional superstructures consisting of the flexible porous coordination polymers, Cu<inf>2</inf>(bdc)<inf>2</inf>(MeOH)<inf>2</inf> and Cu<inf>2</inf>(bdc)<inf>2</inf>(bpy) (bdc<sup>2-</sup> = 1, 4-benzenedicarboxylate, bpy = 4, 4′-bipyridine). Detailed characterization of the replicated systems reveals that the structuralization plays an important role in determining the adsorptive properties of the replicated systems, and that the immobilization of the crystals within a higher-order architecture also affects its structural and dynamic properties. The polyacrylamide polymer is also found to be crucial for maintaining the structuralization of the monolithic systems, and in providing the mechanical robustness required for manual handling. In all, the results discussed here demonstrate a significant expansion in the scope of the coordination replication strategy, and further confirms its utility as a highly versatile platform for the preparation of functional three-dimensional superstructures of porous coordination polymers.
Rights: © The Royal Society of Chemistry 2015.
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
URI: http://hdl.handle.net/2433/210580
DOI(Published Version): 10.1039/c5sc02034d
Appears in Collections:Journal Articles

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