|Title:||Singly and doubly β-to-β platinum-bridged porphyrin dimers and their reductive eliminations|
|Authors:||Jiang, Hua Wei|
Tanaka, Takayuki https://orcid.org/0000-0001-8018-7984 (unconfirmed)
|Author's alias:||田中, 隆行|
|Publisher:||Royal Society of Chemistry|
|Journal title:||Chemical Science|
|Abstract:||2-Borylated porphyrins reacted with Pt(cod)Cl2 to give β-to-β platinum-bridged porphyrin dimers, which were converted to β-to-β directly linked porphyrin dimers through triphenylphosphine-mediated reductive elimination. Similar reactions of 2, 18-diborylated Ni(ii)-porphyrin and Zn(ii)-porphyrin gave the corresponding doubly β-to-β platinum-bridged porphyrin dimers. Treatment of the doubly β-to-β platinum-bridged Ni(ii)-porphyrin dimer with triphenylphosphine caused a single reductive elimination to produce a Ni(ii)-porphyrin dimer possessing a β-to-β platinum bridge and a β-to-β direct C-C bond.|
|Rights:||© The Royal Society of Chemistry.|
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
|Appears in Collections:||Journal Articles|
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