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dc.contributor.author | Jiang, Hua Wei | en |
dc.contributor.author | Tanaka, Takayuki | en |
dc.contributor.author | Osuka, Atsuhiro | en |
dc.contributor.alternative | 田中, 隆行 | ja |
dc.contributor.alternative | 大須賀, 篤弘 | ja |
dc.date.accessioned | 2016-05-12T07:18:02Z | - |
dc.date.available | 2016-05-12T07:18:02Z | - |
dc.date.issued | 2015-07-30 | - |
dc.identifier.issn | 2041-6539 | - |
dc.identifier.uri | http://hdl.handle.net/2433/210581 | - |
dc.description.abstract | 2-Borylated porphyrins reacted with Pt(cod)Cl2 to give β-to-β platinum-bridged porphyrin dimers, which were converted to β-to-β directly linked porphyrin dimers through triphenylphosphine-mediated reductive elimination. Similar reactions of 2, 18-diborylated Ni(ii)-porphyrin and Zn(ii)-porphyrin gave the corresponding doubly β-to-β platinum-bridged porphyrin dimers. Treatment of the doubly β-to-β platinum-bridged Ni(ii)-porphyrin dimer with triphenylphosphine caused a single reductive elimination to produce a Ni(ii)-porphyrin dimer possessing a β-to-β platinum bridge and a β-to-β direct C-C bond. | en |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Royal Society of Chemistry (RSC) | en |
dc.rights | © The Royal Society of Chemistry. | en |
dc.rights | This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. | en |
dc.title | Singly and doubly β-to-β platinum-bridged porphyrin dimers and their reductive eliminations | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.ncid | AA12555653 | - |
dc.identifier.jtitle | Chemical Science | en |
dc.identifier.volume | 6 | - |
dc.identifier.spage | 6102 | - |
dc.identifier.epage | 6105 | - |
dc.relation.doi | 10.1039/c5sc02553b | - |
dc.textversion | publisher | - |
dc.identifier.pmid | 30090224 | - |
dcterms.accessRights | open access | - |
dc.identifier.pissn | 2041-6520 | - |
dc.identifier.eissn | 2041-6539 | - |
出現コレクション: | 学術雑誌掲載論文等 |
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