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タイトル: | Comprehensive Understanding of Structure-Controlling Factors of a Zinc Tetraphenylporphyrin Thin Film Using pMAIRS and GIXD Techniques |
著者: | Hada, Miyako Shioya, Nobutaka https://orcid.org/0000-0002-2915-894X (unconfirmed) Shimoaka, Takafumi https://orcid.org/0000-0001-9131-9831 (unconfirmed) Eda, Kazuo Hada, Masahiko Hasegawa, Takeshi https://orcid.org/0000-0001-5574-9869 (unconfirmed) |
著者名の別形: | 長谷川, 健 |
キーワード: | molecular orientation porphyrinoids/ surface analysis thin films X-ray diffraction |
発行日: | 7-Nov-2016 |
出版者: | Wiley-Blackwell |
誌名: | Chemistry - A European Journal |
巻: | 22 |
号: | 46 |
開始ページ: | 16539 |
終了ページ: | 16546 |
抄録: | The performance of an organic electronic device is significantly influenced by the anisotropic molecular structure in the film, which has long been difficult to predict especially for a solution process. In the present study, a zinc tetraphenylporphyrin (ZnTPP) thin film prepared by a solution process was chosen to comprehensively explore the molecular-arrangement mechanism as a function of representative film-preparation parameters: solvent, film-preparation technique, and thermal annealing. The anisotropic structure was first analyzed by using a combination of infrared p-polarized multiple-angle incidence resolution spectrometry (pMAIRS) and grazing incidence X-ray diffraction (GIXD), which readily revealed the molecular orientation and crystal structure, respectively. As a result, the real dominant factor was found to be the evaporation time of the solvent that determines the initial two different molecular arrangements, types-I and -II, while the thermal annealing was found to play an additional role of improving the molecular order. The correlation between the molecular orientation and the crystal structure was also revealed through the individual orientation analysis of the porphyrin and phenyl rings. |
著作権等: | This is the accepted version of the following article: [M. Hada, N. Shioya, T. Shimoaka, K. Eda, M. Hada, T. Hasegawa, Chem. Eur. J. 2016, 22, 16539], which has been published in final form at http://dx.doi.org/10.1002/chem.201603291. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. The full-text file will be made open to the public on 02 November 2017 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
URI: | http://hdl.handle.net/2433/217224 |
DOI(出版社版): | 10.1002/chem.201603291 |
PubMed ID: | 27699892 |
出現コレクション: | 学術雑誌掲載論文等 |
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