ダウンロード数: 322
このアイテムのファイル:
| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| asia.201402595.pdf | 341.84 kB | Adobe PDF | 見る/開く |
| タイトル: | Activator-free palladium-catalyzed silylation of aryl chlorides with silylsilatranes |
| 著者: | Yamamoto, Yutaro Matsubara, Hiroshi Murakami, Kei Yorimitsu, Hideki    https://orcid.org/0000-0002-0153-1888 (unconfirmed)Osuka, Atsuhiro |
| 著者名の別形: | 依光, 英樹 大須賀, 篤弘 |
| キーワード: | aryl chlorides palladium silylation silylsilatranes transmetalation |
| 発行日: | Jan-2015 |
| 出版者: | John Wiley and Sons Ltd |
| 誌名: | Chemistry - An Asian Journal |
| 巻: | 10 |
| 号: | 1 |
| 開始ページ: | 219 |
| 終了ページ: | 224 |
| 抄録: | The palladium-catalyzed silylation of aryl chlorides with silylsilatranes proceeds under activator-free conditions; hence, wide functional group compatibility is displayed and boryl and siloxy groups are able to survive. Experimental and computational studies revealed that smooth transmetalation from the silylsilatrane to the arylpalladium chloride is facilitated by strong interaction between the Lewis acidic silicon and the chloride. |
| 著作権等: | This is the accepted version of the following article: [Yamamoto, Y., Matsubara, H., Murakami, K., Yorimitsu, H. and Osuka, A. (2015), Activator-Free Palladium-Catalyzed Silylation of Aryl Chlorides with Silylsilatranes. Chem. Asian J., 10: 219–224.], which has been published in final form at https://doi.org/10.1002/asia.201402595. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/218332 |
| DOI(出版社版): | 10.1002/asia.201402595 |
| PubMed ID: | 25123398 |
| 出現コレクション: | 学術雑誌掲載論文等 |
このリポジトリに保管されているアイテムはすべて著作権により保護されています。