ダウンロード数: 243
このアイテムのファイル:
ファイル | 記述 | サイズ | フォーマット | |
---|---|---|---|---|
j.cplett.2015.03.046.pdf | 352.99 kB | Adobe PDF | 見る/開く |
タイトル: | Understanding of the intrinsic difference between normal- and perfluoro-alkyl compounds toward total understanding of material properties |
著者: | Hasegawa, Takeshi https://orcid.org/0000-0001-5574-9869 (unconfirmed) |
著者名の別形: | 長谷川, 健 |
発行日: | 1-May-2015 |
出版者: | Elsevier BV |
誌名: | Chemical Physics Letters |
巻: | 627 |
開始ページ: | 64 |
終了ページ: | 66 |
抄録: | Molecular interaction of perfluoroalkyl (Rf) compounds has long been discussed on an extended theory of normal alkyl compounds. When Rf-specific bulk properties depending on the molecular packing structure are taken into account, however, the conventional polarizability theory has a big inconsistency especially with the high melting point. Here, we present a new viewpoint to totally uniform the conventional theories for systematically accounting for the bulk properties of Rf compounds. With the organized theoretical framework, the conventional understanding based on polarizability proves to be partly true, but it misses the molecular orientation effect, which is specifically necessary for the Rf compounds. |
著作権等: | © 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ The full-text file will be made open to the public on 1 May 2017 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
URI: | http://hdl.handle.net/2433/218620 |
DOI(出版社版): | 10.1016/j.cplett.2015.03.046 |
出現コレクション: | 学術雑誌掲載論文等 |
このリポジトリに保管されているアイテムはすべて著作権により保護されています。