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Title: Magnetic–Nonmagnetic Phase Transition with Interlayer Charge Disproportionation of Nb3 Trimers in the Cluster Compound Nb3Cl8
Authors: Haraguchi, Yuya
Michioka, Chishiro  kyouindb  KAKEN_id
Ishikawa, Manabu
Nakano, Yoshiaki  kyouindb  KAKEN_id  orcid (unconfirmed)
Yamochi, Hideki
Ueda, Hiroaki  kyouindb  KAKEN_id
Yoshimura, Kazuyoshi  kyouindb  KAKEN_id
Author's alias: 原口, 祐哉
道岡, 千城
石川, 学
中野, 義明
矢持, 秀起
植田, 浩明
吉村, 一良
Issue Date: 10-Feb-2017
Publisher: American Chemical Society (ACS)
Journal title: Inorganic Chemistry
Volume: 56
Issue: 6
Start page: 3483
End page: 3488
Abstract: We grew large single crystals of the cluster magnet Nb3Cl8 with a magnetic triangular lattice and investigated its magnetic properties and crystal structure. In Nb3Cl8, the [Nb3]8+ cluster has a single unpaired spin, making it an S = 1/2 triangular lattice anti-ferromagnet. At low temperatures, Nb3Cl8 exhibits a magnetic–nonmagnetic phase transition driven by a charge disproportionation, in which the paramagnetic [Nb3]8+ clusters transform into alternating layers of nonmagnetic [Nb3]7+ and [Nb3]9+ clusters. The observed exotic phenomenon with the strong correlation between the magnetism and structure are based on the nature of the cluster magnetism.
Rights: This document is the Accepted Manuscript version of a Published Work that appeared in final form in 'Inorganic Chemistry', copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see
The full-text file will be made open to the public on 10 February 2018 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
DOI(Published Version): 10.1021/acs.inorgchem.6b03028
Appears in Collections:Journal Articles

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