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| File | Description | Size | Format | |
|---|---|---|---|---|
| acs.inorgchem.6b03028.pdf | 2.07 MB | Adobe PDF | View/Open |
| Title: | Magnetic–Nonmagnetic Phase Transition with Interlayer Charge Disproportionation of Nb3 Trimers in the Cluster Compound Nb3Cl8 |
| Authors: | Haraguchi, Yuya Michioka, Chishiro   Ishikawa, Manabu Nakano, Yoshiaki  https://orcid.org/0000-0003-3616-7286 (unconfirmed)Yamochi, Hideki Ueda, Hiroaki Yoshimura, Kazuyoshi |
| Author's alias: | 原口, 祐哉 道岡, 千城 石川, 学 中野, 義明 矢持, 秀起 植田, 浩明 吉村, 一良 |
| Issue Date: | 10-Feb-2017 |
| Publisher: | American Chemical Society (ACS) |
| Journal title: | Inorganic Chemistry |
| Volume: | 56 |
| Issue: | 6 |
| Start page: | 3483 |
| End page: | 3488 |
| Abstract: | We grew large single crystals of the cluster magnet Nb3Cl8 with a magnetic triangular lattice and investigated its magnetic properties and crystal structure. In Nb3Cl8, the [Nb3]8+ cluster has a single unpaired spin, making it an S = 1/2 triangular lattice anti-ferromagnet. At low temperatures, Nb3Cl8 exhibits a magnetic–nonmagnetic phase transition driven by a charge disproportionation, in which the paramagnetic [Nb3]8+ clusters transform into alternating layers of nonmagnetic [Nb3]7+ and [Nb3]9+ clusters. The observed exotic phenomenon with the strong correlation between the magnetism and structure are based on the nature of the cluster magnetism. |
| Rights: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in 'Inorganic Chemistry', copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://doi.org/10.1021/acs.inorgchem.6b03028. The full-text file will be made open to the public on 10 February 2018 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/219444 |
| DOI(Published Version): | 10.1021/acs.inorgchem.6b03028 |
| Appears in Collections: | Journal Articles |
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