Access count of this item: 79
|Title:||Magnetic–Nonmagnetic Phase Transition with Interlayer Charge Disproportionation of Nb3 Trimers in the Cluster Compound Nb3Cl8|
Nakano, Yoshiaki https://orcid.org/0000-0003-3616-7286 (unconfirmed)
|Author's alias:||原口, 祐哉|
|Publisher:||American Chemical Society (ACS)|
|Journal title:||Inorganic Chemistry|
|Abstract:||We grew large single crystals of the cluster magnet Nb3Cl8 with a magnetic triangular lattice and investigated its magnetic properties and crystal structure. In Nb3Cl8, the [Nb3]8+ cluster has a single unpaired spin, making it an S = 1/2 triangular lattice anti-ferromagnet. At low temperatures, Nb3Cl8 exhibits a magnetic–nonmagnetic phase transition driven by a charge disproportionation, in which the paramagnetic [Nb3]8+ clusters transform into alternating layers of nonmagnetic [Nb3]7+ and [Nb3]9+ clusters. The observed exotic phenomenon with the strong correlation between the magnetism and structure are based on the nature of the cluster magnetism.|
|Rights:||This document is the Accepted Manuscript version of a Published Work that appeared in final form in 'Inorganic Chemistry', copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://doi.org/10.1021/acs.inorgchem.6b03028.|
The full-text file will be made open to the public on 10 February 2018 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
|Appears in Collections:||Journal Articles|
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.