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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| molecules21101309.pdf | 2.14 MB | Adobe PDF | 見る/開く |
| タイトル: | Synthesis of a 1-Aryl-2,2-chlorosilyl(phospha)silene Coordinated by an N-Heterocyclic Carbene |
| 著者: | Kyri, Andreas Majhi, Paresh Sasamori, Takahiro Agou, Tomohiro Nesterov, Vitaly Guo, Jing-Dong Nagase, Shigeru Tokitoh, Norihiro    https://orcid.org/0000-0003-1083-7245 (unconfirmed)Streubel, Rainer |
| 著者名の別形: | 笹森, 貴裕 吾郷, 友宏 永瀬, 茂 時任, 宣博 |
| キーワード: | main group elements phosphasilene N-heterocyclic |
| 発行日: | 30-Sep-2016 |
| 出版者: | MDPI AG |
| 誌名: | Molecules |
| 巻: | 21 |
| 号: | 10 |
| 論文番号: | 1309 |
| 抄録: | Phosphasilenes, P=Si doubly bonded compounds, have received considerable attention due to their unique physical and chemical properties. We report on the synthesis and structure of a chlorophosphasilene coordinated by an N-heterocyclic carbene (NHC), which has the potential of functionalization at the Si–Cl moiety. Treatment of a silylphosphine, ArPH–SiCl2RSi (Ar = bulky aryl group, RSi = Si(SiMe3)3) with two equivalents of Im-Me4 (1, 3, 4, 5-tetramethylimidazol-2-ylidene) afforded the corresponding NHC-coordinated phosphasilene, ArP=SiClRSi(Im-Me4) as a stable compound. Bonding properties of the P=Si bond coordinated to an NHC will be discussed on the basis of theoretical calculations. |
| 著作権等: | This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0). |
| URI: | http://hdl.handle.net/2433/223003 |
| DOI(出版社版): | 10.3390/molecules21101309 |
| PubMed ID: | 27706036 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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