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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| 1.4996226.pdf | 6.46 MB | Adobe PDF | 見る/開く |
| タイトル: | Interface structure between tetraglyme and graphite |
| 著者: | Minato, Taketoshi Araki, Yuki Umeda, Kenichi Yamanaka, Toshiro  Okazaki, Ken-ichi Onishi, Hiroshi Abe, Takeshi Ogumi, Zempachi |
| 著者名の別形: | 湊, 丈俊 荒木, 優希 梅田, 健一 山中, 俊朗 岡崎, 健一 大西, 洋 安部, 武志 小久見, 善八 |
| キーワード: | Interface Carbon based materials Atomic force microscopy Batteries Density functional theory |
| 発行日: | 25-Sep-2017 |
| 出版者: | AIP Publishing |
| 誌名: | The Journal of Chemical Physics |
| 巻: | 147 |
| 号: | 12 |
| 論文番号: | 124701 |
| 抄録: | Clarification of the details of the interface structure between liquids and solids is crucial for understanding the fundamental processes of physical functions. Herein, we investigate the structure of the interface between tetraglyme and graphite and propose a model for the interface structure based on the observation of frequency-modulation atomic force microscopy in liquids. The ordering and distorted adsorption of tetraglyme on graphite were observed. It is found that tetraglyme stably adsorbs on graphite. Density functional theory calculations supported the adsorption structure. In the liquid phase, there is a layered structure of the molecular distribution with an average distance of 0.60 nm between layers. |
| 著作権等: | © 2017 AIP Publishing. This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing. The following article appeared in 'The Journal of Chemical Physics 147, 124701 (2017)' and may be found at http://aip.scitation.org/doi/10.1063/1.4996226. The full-text file will be made open to the public on 25 September 2018 accordance with publisher's 'Terms and Conditions for Self-Archiving'. |
| URI: | http://hdl.handle.net/2433/229001 |
| DOI(出版社版): | 10.1063/1.4996226 |
| PubMed ID: | 28964018 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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