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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| acs.orglett.8b00060.pdf | 596.75 kB | Adobe PDF | 見る/開く |
| タイトル: | Palladium-Catalyzed Amination of Aryl Sulfoxides |
| 著者: | Yoshida, Yuto Otsuka, Shinya Nogi, Keisuke   https://orcid.org/0000-0001-8478-1227 (unconfirmed)Yorimitsu, Hideki  https://orcid.org/0000-0002-0153-1888 (unconfirmed) |
| 著者名の別形: | 吉田, 悠人 大塚, 慎也 野木, 馨介 依光, 英樹 |
| 発行日: | 16-Feb-2018 |
| 出版者: | American Chemical Society (ACS) |
| 誌名: | Organic Letters |
| 巻: | 20 |
| 号: | 4 |
| 開始ページ: | 1134 |
| 終了ページ: | 1137 |
| 抄録: | Amination of diaryl sulfoxides with anilines and alkylamines has been accomplished under palladium/N-heterocyclic carbene (NHC) catalysis. Owing to its electron deficiency, the leaving arenesulfenate anion would be smoothly released from the palladium center to result in uneventful catalyst turnover under milder reaction conditions in comparison with previous C–S bond amination reactions. This amination accommodated a wider range of functional groups such as silyl, boryl, methylsulfanyl, and halogen moieties. Regioselective amination of unsymmetrical diaryl sulfoxides was also executed by means of steric bias. |
| 著作権等: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in 'Organic Letters', copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.8b00060. The full-text file will be made open to the public on 2 February 2019 in accordance with publisher's 'Terms and Conditions for Self-Archiving' This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/229509 |
| DOI(出版社版): | 10.1021/acs.orglett.8b00060 |
| PubMed ID: | 29393652 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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