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Title: Light-melt adhesive based on dynamic carbon frameworks in a columnar liquid crystal phase
Authors: Saito, Shohei  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0003-1863-9956 (unconfirmed)
Nobusue, Shunpei  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0002-6739-3465 (unconfirmed)
Tsuzaka, Eri
Yuan, Chunxue
Mori, Chigusa
Hara, Mitsuo
Seki, Takahiro
Camacho, Cristopher
Irle, Stephan
Yamaguchi, Shigehiro
Author's alias: 齊藤, 尚平
Issue Date: 4-Jul-2016
Publisher: Springer Nature
Journal title: Nature Communications
Volume: 7
Thesis number: 12094
Abstract: Liquid crystal (LC) provides a suitable platform to exploit structural motions of molecules in a condensed phase. Amplification of the structural changes enables a variety of technologies not only in LC displays but also in other applications. Until very recently, however, a practical use of LCs for removable adhesives has not been explored, although a spontaneous disorganization of LC materials can be easily triggered by light-induced isomerization of photoactive components. The difficulty of such application derives from the requirements for simultaneous implementation of sufficient bonding strength and its rapid disappearance by photoirradiation. Here we report a dynamic molecular LC material that meets these requirements. Columnar-stacked V-shaped carbon frameworks display sufficient bonding strength even during heating conditions, while its bonding ability is immediately lost by a light-induced self-melting function. The light-melt adhesive is reusable and its fluorescence colour reversibly changes during the cycle, visualizing the bonding/nonbonding phases of the adhesive.
Rights: This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
URI: http://hdl.handle.net/2433/233161
DOI(Published Version): 10.1038/ncomms12094
PubMed ID: 27373592
Appears in Collections:Journal Articles

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