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Title: Synthesis of a Dichlorodigermasilane: Double Si–Cl Activation by a Ge=Ge Unit
Authors: Sugahara, Tomohiro
Tokitoh, Norihiro  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0003-1083-7245 (unconfirmed)
Sasamori, Takahiro
Author's alias: 菅原, 知紘
時任, 宣博
笹森, 貴裕
Keywords: Si–Cl activation
germylene
digermene
digermacyclobutadiene
Issue Date: 14-Nov-2017
Publisher: MDPI AG
Journal title: Inorganics
Volume: 5
Issue: 4
Thesis number: 79
Abstract: Halogenated oligosilanes and oligogermanes are interesting compounds in oligosilane chemistry from the viewpoint of silicon-based-materials. Herein, it was demonstrated that a 1, 2-digermacyclobutadiene derivative could work as a bis-germylene building block towards double Si–Cl activation to give a halogenated oligometallane, a bis(chlorogermyl)dichlorosilane derivative.
Rights: © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).
URI: http://hdl.handle.net/2433/233933
DOI(Published Version): 10.3390/inorganics5040079
Appears in Collections:Journal Articles

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