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Title: Chemical Adsorption and Physical Confinement of Polysulfides with the Janus-faced Interlayer for High-performance Lithium-Sulfur Batteries
Authors: Chiochan, Poramane
Kaewruang, Siriroong
Phattharasupakun, Nutthaphon
Wutthiprom, Juthaporn
Maihom, Thana
Limtrakul, Jumras
Nagarkar, Sanjog S.
Horike, Satoshi  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0001-8530-6364 (unconfirmed)
Sawangphruk, Montree
Author's alias: 堀毛, 悟史
Keywords: Batteries
Issue Date: 18-Dec-2017
Publisher: Springer Nature
Journal title: Scientific Reports
Volume: 7
Thesis number: 17703
Abstract: We design the Janus-like interlayer with two different functional faces for suppressing the shuttle of soluble lithium polysulfides (LPSs) in lithium-sulfur batteries (LSBs). At the front face, the conductive functionalized carbon fiber paper (f-CFP) having oxygen-containing groups i.e., -OH and -COOH on its surface was placed face to face with the sulfur cathode serving as the first barrier accommodating the volume expansion during cycling process and the oxygen-containing groups can also adsorb the soluble LPSs via lithium bonds. At the back face, a crystalline coordination network of [Zn(H2PO4)2(TzH)2]n (ZnPTz) was coated on the back side of f-CFP serving as the second barrier retarding the left LPSs passing through the front face via both physical confinement and chemical adsorption (i.e. Li bonding). The LSB using the Janus-like interlayer exhibits a high reversible discharge capacity of 1, 416 mAh g−1 at 0.1C with a low capacity fading of 0.05% per cycle, 92% capacity retention after 200 cycles and ca. 100% coulombic efficiency. The fully charged LSB cell can practically supply electricity to a spinning motor with a nominal voltage of 3.0 V for 28 min demonstrating many potential applications.
Description: An Author Correction to this article was published on 01 June 2018.
Rights: © The Author(s) 2017. This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
URI: http://hdl.handle.net/2433/234972
DOI(Published Version): 10.1038/s41598-017-18108-0
PubMed ID: 29255307
Related Link: https://doi.org/10.1038/s41598-018-24801-5
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