ダウンロード数: 238
このアイテムのファイル:
| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| c8cp04292f.pdf | 452.24 kB | Adobe PDF | 見る/開く |
| タイトル: | Visible-light photoexcitation of pyridine surface complex, leading to selective dehydrogenative cross-coupling with cyclohexane |
| 著者: | Naniwa, Shimpei Tyagi, Akanksha Yamamoto, Akira    https://orcid.org/0000-0002-1329-0807 (unconfirmed)Yoshida, Hisao https://orcid.org/0000-0002-2540-0225 (unconfirmed) |
| 著者名の別形: | 浪花, 晋平 山本, 旭 吉田, 寿雄 |
| 発行日: | 7-Dec-2018 |
| 出版者: | Royal Society of Chemistry (RSC) |
| 誌名: | Physical Chemistry Chemical Physics |
| 巻: | 20 |
| 号: | 45 |
| 開始ページ: | 28375 |
| 終了ページ: | 28381 |
| 抄録: | Upon photoirradiation with visible light, a pyridine molecule adsorbed on a TiO₂ surface can be photoexcited to give a pyridine radical cation via ligand-to-metal charge transfer (LMCT) between pyridine and titanium. This leads to dehydrogenative cross-coupling (DCC) between pyridine and cyclohexane with concomitant hydrogen evolution. Since the radical cation can selectively oxidize cyclohexane to a cyclohexyl radical, the cross-coupling between pyridine and cyclohexane proceeds with higher selectivity compared with that in photocatalysis by TiO₂ under UV irradiation. |
| 著作権等: | This is the accepted manuscript of the article, which has been published in final form at https://doi.org/10.1039/C8CP04292F. The full-text file will be made open to the public on 18 August 2019 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
| URI: | http://hdl.handle.net/2433/235622 |
| DOI(出版社版): | 10.1039/c8cp04292f |
| PubMed ID: | 30182096 |
| 出現コレクション: | 学術雑誌掲載論文等 |
このリポジトリに保管されているアイテムはすべて著作権により保護されています。