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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| acs.orglett.7b02122.pdf | 762.83 kB | Adobe PDF | 見る/開く |
| タイトル: | Synthesis of Octahydro- and Decahydroquinolines by a One-Pot Cascade Reaction of Tetrasubstituted Enecarbamate |
| 著者: | Kurose, Tomohiro Tsukano, Chihiro    https://orcid.org/0000-0002-9361-0857 (unconfirmed)Takemoto, Yoshiji https://orcid.org/0000-0003-1375-3821 (unconfirmed) |
| 著者名の別形: | 黒瀬, 朋浩 塚野, 千尋 竹本, 佳司 |
| 発行日: | 15-Sep-2017 |
| 出版者: | American Chemical Society |
| 誌名: | Organic Letters |
| 巻: | 19 |
| 号: | 18 |
| 開始ページ: | 4762 |
| 終了ページ: | 4765 |
| 抄録: | A transition-metal-catalyzed cyclopropanation followed by ring opening was investigated for the synthesis of octahydroquinolines 4 and decahydroquinolines 5 having a quaternary carbon center at the angular position, which are core structures of the fawcettimine-type alkaloids. A tandem reaction was also established for the synthesis of decahydroquinolines 5 and the tricyclic compound 6 through an iminium ion intermediate, readily produced by acidic treatment of cyclopropane 2. |
| 著作権等: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.7b02122. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/235944 |
| DOI(出版社版): | 10.1021/acs.orglett.7b02122 |
| PubMed ID: | 28880096 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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