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ファイル | 記述 | サイズ | フォーマット | |
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acssuschemeng.8b05552.pdf | 1.38 MB | Adobe PDF | 見る/開く |
タイトル: | Ionic Conduction in Metal-Organic Frameworks with Incorporated Ionic Liquids |
著者: | Yoshida, Yukihiro https://orcid.org/0000-0003-4630-9559 (unconfirmed) Kitagawa, Hiroshi https://orcid.org/0000-0001-6955-3015 (unconfirmed) |
著者名の別形: | 吉田, 幸大 北川, 宏 |
キーワード: | Acidity/basicity Ionic conductivity Ionic liquids Metal-organic frameworks Porous materials |
発行日: | 7-Jan-2018 |
出版者: | American Chemical Society |
誌名: | ACS Sustainable Chemistry and Engineering |
巻: | 7 |
号: | 1 |
開始ページ: | 70 |
終了ページ: | 81 |
抄録: | Encapsulation of ionic liquids (ILs) into porous materials can provide environmentally benign solid-state electrolytes for various electrochemical devices, in particular, porous metal–organic frameworks (MOFs) that enable us to tailor their framework and pore structures by varying central metals and organic linkers as well as the ILs with an unlimited number of possible cation–anion combinations. Therefore, rational materials design based on the accumulated knowledge about the relationship between materials and functionalities is essential for studying IL@MOF hybrid composites with desired properties. In this Review, we first introduce synthetic methodologies to incorporate ILs into MOFs, especially based on the postimpregnation approach. Interactions and the distribution of component ions of the ILs within the MOFs are discussed from the viewpoint of ion mobility, which is responsible for the performance of electrochemical devices. Finally, we devote attention to the ion-conducting properties, including lithium ion, proton, and hydroxide conductions, of the hybrid composites. |
著作権等: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Sustainable Chemistry and Engineering, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acssuschemeng.8b05552. The full-text file will be made open to the public on 06 December 2019 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
URI: | http://hdl.handle.net/2433/235948 |
DOI(出版社版): | 10.1021/acssuschemeng.8b05552 |
出現コレクション: | 学術雑誌掲載論文等 |
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