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polym10070775.pdf | 6.38 MB | Adobe PDF | 見る/開く |
タイトル: | Chain Trajectory, Chain Packing, and Molecular Dynamics of Semicrystalline Polymers as Studied by Solid-State NMR |
著者: | Wang, Shijun Hong, You-Lee Yuan, Shichen Chen, Wei Zhou, Wenxuan Li, Zhen Wang, Kun Min, Xu Konishi, Takashi https://orcid.org/0000-0003-1134-5445 (unconfirmed) Miyoshi, Toshikazu |
著者名の別形: | 小西, 隆士 |
キーワード: | chain trajectory chain packing molecular dynamics semicrystalline polymer polymer crystallization solid-state NMR |
発行日: | Jul-2018 |
出版者: | MDPI AG |
誌名: | Polymers |
巻: | 10 |
号: | 7 |
論文番号: | 775 |
抄録: | Chain-level structure of semicrystalline polymers in melt- and solution-grown crystals has been debated over the past half century. Recently, ¹³C-¹³C double quantum (DQ) Nuclear Magnetic Resonance (NMR) spectroscopy has been successfully applied to investigate chain-folding (CF) structure and packing structure of ¹³C enriched polymers after solution and melt crystallization. We review recent NMR studies for (i) packing structure, (ii) chain trajectory, (iii) conformation of the folded chains, (iv) nucleation mechanisms, (v) deformation mechanism, and (vi) molecular dynamics of semicrystalline polymers. |
著作権等: | © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
URI: | http://hdl.handle.net/2433/236475 |
DOI(出版社版): | 10.3390/polym10070775 |
PubMed ID: | 30960700 |
出現コレクション: | 学術雑誌掲載論文等 |
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