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matertrans.MBW201310.pdf | 1.74 MB | Adobe PDF | 見る/開く |
タイトル: | Fabrication and Catalytic Decoloration Capacity of Nanodendritic Metals |
著者: | Hakamada, Masataka https://orcid.org/0000-0002-8082-2148 (unconfirmed) Matsuzawa, Takayuki Mabuchi, Mamoru https://orcid.org/0000-0002-0894-6306 (unconfirmed) |
著者名の別形: | 袴田, 昌高 松澤, 崇之 馬渕, 守 |
キーワード: | dendrite square-wave potential pulse gold palladium catalyst decoloration high-index facet edge |
発行日: | 1-Mar-2014 |
出版者: | Japan Institute of Metals and Materials |
誌名: | Materials Transactions |
巻: | 55 |
号: | 3 |
開始ページ: | 534 |
終了ページ: | 538 |
抄録: | Nanodendritic Pd was fabricated by square-wave potential pulse (SWPP) electrolysis on Pd surface. Dendrite cell sizes and dendrite arm spacings were well below 100 nm and decreased with the increase in the frequency of SWPP. Cyclic voltammetry revealed that true surface area of Pd increased by up to 57 times by the nanodendritic structure. Nanodendritic Au was also fabricated by SWPP and its catalytic decoloration capacity was compared with that of nanoporous Au. Nanodendritic Au decomposed methyl orange more efficiently than nanoporous Au. This may be attributed to high-index facets and edges commonly found in nanodendritic structures synthesized by SWPP electrolysis. |
著作権等: | © 2013 The Japan Institute of Metals and Materials Publisher permitted to deposit this paper on this repository. 発行元の許可を得て登録しています. |
URI: | http://hdl.handle.net/2433/237648 |
DOI(出版社版): | 10.2320/matertrans.MBW201310 |
出現コレクション: | 学術雑誌掲載論文等 |
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