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2.0481803jes.pdf | 1.01 MB | Adobe PDF | 見る/開く |
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dc.contributor.author | Kitada, Atsushi | en |
dc.contributor.author | Takeoka, Shun | en |
dc.contributor.author | Kintsu, Kohei | en |
dc.contributor.author | Fukami, Kazuhiro | en |
dc.contributor.author | Saimura, Masayuki | en |
dc.contributor.author | Nagata, Takashi | en |
dc.contributor.author | Katahira, Masato | en |
dc.contributor.author | Murase, Kuniaki | en |
dc.contributor.alternative | 北田, 敦 | ja |
dc.contributor.alternative | 竹岡, 駿 | ja |
dc.contributor.alternative | 近都, 康平 | ja |
dc.contributor.alternative | 深見, 一弘 | ja |
dc.contributor.alternative | 永田, 崇 | ja |
dc.contributor.alternative | 片平, 正人 | ja |
dc.contributor.alternative | 邑瀬, 邦明 | ja |
dc.date.accessioned | 2019-04-05T03:00:22Z | - |
dc.date.available | 2019-04-05T03:00:22Z | - |
dc.date.issued | 2018-02-22 | - |
dc.identifier.issn | 0013-4651 | - |
dc.identifier.uri | http://hdl.handle.net/2433/240665 | - |
dc.description | This was Paper 3475 presented at the Honolulu, Hawaii, Meeting of the Society, October 2–7, 2016. | en |
dc.description.abstract | A new kind of ionic liquid (IL) with strong Brønsted acidity, i.e., a hydronium (H₃O⁺) solvate ionic liquid, is reported. The IL can be described as [H₃O⁺·18C6]Tf₂N, where water exists as the H₃O⁺ ion solvated by 18-crown-6-ether (18C6), of which the counter anion is bis(trifluoromethylsulfonyl)amide (Tf₂N⁻; Tf = CF₃SO₂). The hydrophobic Tf₂N⁻ anion makes [H₃O⁺·18C6]Tf₂N, evaluated using the indicator method, is a new record for ILs and indicates strong aciditiy. The findings regarding this proton-condensed solvate IL are of fundamental interest, and will help in the design of media for new acid-base reactions. | en |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | The Electrochemical Society | en |
dc.rights | © The Author(s) 2018. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited. | en |
dc.subject | acidity | en |
dc.subject | hydronium | en |
dc.subject | solvate ionic liquid | en |
dc.title | A Hydronium Solvate Ionic Liquid: Facile Synthesis of Air-Stable Ionic Liquid with Strong Bronsted Acidity | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.jtitle | Journal of the Electrochemical Society | en |
dc.identifier.volume | 165 | - |
dc.identifier.issue | 3 | - |
dc.identifier.spage | H121 | - |
dc.identifier.epage | H127 | - |
dc.relation.doi | 10.1149/2.0481803jes | - |
dc.textversion | publisher | - |
dc.address | Department of Materials Science and Engineering, Kyoto University | en |
dc.address | Department of Materials Science and Engineering, Kyoto University | en |
dc.address | Department of Materials Science and Engineering, Kyoto University | en |
dc.address | Department of Materials Science and Engineering, Kyoto University | en |
dc.address | Institute of Advanced Energy, Gokasho, Uji | en |
dc.address | Institute of Advanced Energy, Gokasho, Uji | en |
dc.address | Institute of Advanced Energy, Gokasho, Uji | en |
dc.address | Department of Materials Science and Engineering, Kyoto University | en |
dcterms.accessRights | open access | - |
datacite.awardNumber | 25249106 | - |
datacite.awardNumber | 16H02411 | - |
datacite.awardNumber | 15K14193 | - |
datacite.awardNumber | 15K18253 | - |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
出現コレクション: | 学術雑誌掲載論文等 |
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