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j.jaap.2007.09.005.pdf | 1.2 MB | Adobe PDF | 見る/開く |
タイトル: | Different action of alkali/alkaline earth metal chlorides on cellulose pyrolysis |
著者: | Shimada, Naoki Kawamoto, Haruo https://orcid.org/0000-0002-4934-8054 (unconfirmed) Saka, Shiro |
著者名の別形: | 島田, 有樹 河本, 晴雄 坂, 志朗 |
キーワード: | Cellulose Pyrolysis Influence of metal chloride Alkali metal Alkaline earth metal NaCl KCl MgCl₂ CaCl₂ Thermogravimetry Differential thermal analysis |
発行日: | Jan-2008 |
出版者: | Elsevier BV |
誌名: | Journal of Analytical and Applied Pyrolysis |
巻: | 81 |
号: | 1 |
開始ページ: | 80 |
終了ページ: | 87 |
抄録: | The influence of alkali metal chlorides (NaCl, KCl) and alkaline earth metal chlorides (MgCl₂, CaCl₂) on cellulose pyrolysis was studied with thermal analysis and isothermal pyrolysis in N₂ at 150–400 °C. Alkali and alkaline earth metal chlorides affected the cellulose pyrolysis in different way. Although alkali metal chlorides did not change the weight loss temperature of bulk cellulose (main part of cellulose) so much, alkaline earth metal chlorides substantially reduced the temperature. Furthermore, the influence of alkaline earth metal chlorides on the weight loss behavior (<400 °C) was very dependent on the amount of loading bellow 0.30 mol/mol of the glucose-unit of cellulose, while the influences of the alkali metal chlorides were almost independent of the amount. Both metal chlorides significantly changes the low MW product composition even at a very low level of addition. |
著作権等: | © 2007. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ The full-text file will be made open to the public on 1 January 2010 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
URI: | http://hdl.handle.net/2433/240764 |
DOI(出版社版): | 10.1016/j.jaap.2007.09.005 |
出現コレクション: | 学術雑誌掲載論文等 |
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