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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| j.carres.2007.04.009.pdf | 502.46 kB | Adobe PDF | 見る/開く |
| タイトル: | Solid-state hydrolysis of cellulose and methyl α- and β-d-glucopyranosides in presence of magnesium chloride |
| 著者: | Shimada, Naoki Kawamoto, Haruo    https://orcid.org/0000-0002-4934-8054 (unconfirmed)Saka, Shiro |
| 著者名の別形: | 島田, 有樹 河本, 晴雄 坂, 志朗 |
| キーワード: | Cellulose Magnesium chloride Hydrolysis Solid-state hydrolysis Methyl α- and β-d-Glucopyranosides Lewis acid |
| 発行日: | 23-Jul-2007 |
| 出版者: | Elsevier BV |
| 誌名: | Carbohydrate Research |
| 巻: | 342 |
| 号: | 10 |
| 開始ページ: | 1373 |
| 終了ページ: | 1377 |
| 抄録: | Solid-state hydrolysis proceeded with cellulose and methyl α- and β-d-glucopyranosides in the presence of hydrated magnesium chloride. This reaction was effective even at >100 °C since the hydrated water, which is held by MgCl₂ up to >200 °C, is utilized as a nucleophile. Excess water made this reaction ineffective due to the competition between water and sugar oxygen atoms in coordinating with Mg²⁺, a Lewis acid. Consequently, this hydrolysis reaction is characteristic of solid-state reactions. |
| 著作権等: | © 2007. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ The full-text file will be made open to the public on 23 July 2009 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/240767 |
| DOI(出版社版): | 10.1016/j.carres.2007.04.009 |
| PubMed ID: | 17498675 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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